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Elimination reactions and reaction with metals sheet
5-mark answer frame

Explain with equations: (i) dehydrohalogenation and Zaitsev's rule, (ii) the Wurtz reaction, (iii) the preparation of a Grignard reagent, and why it must be kept dry.

How to lay out the answer. Follow the frame, then write it in your own words.

  1. 1 · Define elimination. In β-elimination, H from the β-carbon and X from the α-carbon are removed, giving an alkene.
  2. 2 · Zaitsev example.
    • CH₃CH₂CH₂CH(Br)CH₃ + KOH (alc) → pent-2-ene (major) + pent-1-ene (minor)
    • Rule: the more substituted alkene is the major product
  3. 3 · Wurtz reaction. 2CH₃Br + 2Na (dry ether) → CH₃-CH₃ + 2NaBr.
  4. 4 · Grignard reagent. CH₃CH₂Br + Mg (dry ether) → CH₃CH₂MgBr.
  5. 5 · Why it must be dry. CH₃CH₂MgBr + H₂O → CH₃CH₃ + Mg(OH)Br; any proton source destroys the reagent.
  6. 6 · Close in one line. So the reagent and solvent decide whether a haloalkane gives an alcohol, an alkene or a new C-C bond.

Scoring tip: Write 'alcoholic' or 'dry ether' above the arrow; without it the equation loses a mark.