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Reversible and irreversible reactions; chemical equilibrium sheet
7-mark answer frame

Distinguish between reversible and irreversible reactions. What is chemical equilibrium? Give its characteristics.

How to lay out the answer. Follow the frame, then write it in your own words.

  1. 1 · Reversible reaction. Goes in both directions under the same conditions: N₂ + 3H₂ ⇌ 2NH₃.
  2. 2 · Irreversible reaction. Goes in one direction only, to completion: burning of paper, 2Mg + O₂ → 2MgO.
  3. 3 · Differences.
    • Both ways vs one way
    • ⇌ vs →
    • Reaches equilibrium vs goes to completion
    • Closed vessel vs open vessel
  4. 4 · Define equilibrium. The state of a reversible reaction in which the forward and backward rates are equal and concentrations stay constant.
  5. 5 · Draw the rate graph. [Graph of rate against time: the forward rate curve falls, the backward rate curve rises, they meet and run flat together; mark 'equilibrium']
  6. 6 · Characteristics.
    • Reached only in a closed system
    • Dynamic: both reactions continue
    • Concentrations constant
    • Reached from either side
    • Catalyst does not change it
  7. 7 · Real-life link. A closed soda bottle holds CO₂ at equilibrium; cooking an egg is irreversible.
  8. 8 · Close in one line. Thus equilibrium is a balance of two reactions running at equal rates, not a stop.

Scoring tip: Use the ⇌ sign in every reversible example and say the word 'dynamic' with a reason.