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Naming organic compounds (IUPAC system) sheet
4-mark answer frame

Explain the IUPAC rules for naming organic compounds, with two examples.

How to lay out the answer. Follow the frame, then write it in your own words.

  1. 1 · One line on IUPAC. An IUPAC name shows the chain length, the type of bond and the functional group of a compound.
  2. 2 · Write the four parts. Prefix + word root + primary suffix + secondary suffix.
  3. 3 · Write the rules.
    • Choose the longest carbon chain for the word root.
    • Number from the end nearer the functional group or side group.
    • Add -ane, -ene or -yne for the bond type.
    • Add -ol, -al, -one or -oic acid for the functional group; drop the 'e' before a vowel.
  4. 4 · Show two examples with structures. CH₃-CH₂-CH₂-OH is propan-1-ol. CH₃-CO-CH₃ is propanone.
  5. 5 · Real life. Nail-polish remover is propanone; vinegar contains ethanoic acid.
  6. 6 · Close in one line. So one name gives one structure, everywhere in the world.

Scoring tip: Split each example name into its parts (prop | an | ol). Examiners give marks for the parts as well as the final name.