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Unit II · Electrostatic potential and capacitance
10 min readConcept sheet2 or 3-mark numericals on the energy of two or three charges, and a 3-mark derivation of U = −pE cos θ; also a NEET favourite

Potential energy of a system of charges and of a dipole in a field

Two charges store U = q₁q₂/(4πε₀r), the work done to bring them together from infinity. A dipole in a uniform field has U = −pE cos θ.

Two chargesU = (1/4πε₀) q₁q₂/r₁₂; positive for like charges, negative for unlike charges
Three chargesU = (1/4πε₀)(q₁q₂/r₁₂ + q₁q₃/r₁₃ + q₂q₃/r₂₃): add over every pair
Dipole in a uniform fieldU(θ) = −pE cos θ = −p·E, taking U = 0 at θ = 90°
Work to turn a dipoleW = pE(cos θ₁ − cos θ₂) to turn it from θ₁ to θ₂

Derivation: potential energy of two point charges

Build the system by bringing q₁ and then q₂ from infinity, slowly. The work done is stored as potential energy U.

  1. 1
    Bring q₁ to its place first. No other charge is present, so no work is needed.
  2. 2
    q₁ now sets up a potential V₁ = q₁/(4πε₀r₁₂) at the place where q₂ will go.
  3. 3
    Bring q₂ from infinity to that place. Work done = q₂ × V₁ = q₁q₂/(4πε₀r₁₂).
  4. 4★
    So, U = (1/4πε₀) q₁q₂/r₁₂. The force is conservative, so U does not depend on the order or the path.
  5. 5
    If q₁q₂ > 0 (like charges), U > 0: work is done to push them together. If q₁q₂ < 0, U < 0.

★ key step

Three or more charges

For more charges, add the energy of every pair, counting each pair once. For three charges: U = (1/4πε₀)(q₁q₂/r₁₂ + q₁q₃/r₁₃ + q₂q₃/r₂₃). For a single charge q placed in an external potential V, the potential energy is simply U = qV. A negative U means the system is bound: work must be supplied to pull the charges apart to infinity.

Derivation: potential energy of a dipole in a uniform field

A dipole of moment p is in a uniform field E. The torque on it is τ = pE sin θ.

  1. 1
    Turn the dipole slowly from angle θ₀ to θ₁ with an external torque equal and opposite to τ.
  2. 2
    Work done = ∫ pE sin θ dθ, with θ going from θ₀ to θ₁.
  3. 3
    Since ∫ sin θ dθ = −cos θ, W = pE(cos θ₀ − cos θ₁).
  4. 4
    This work is stored as the change in potential energy: U(θ₁) − U(θ₀) = pE(cos θ₀ − cos θ₁).
  5. 5
    Choose U = 0 when the dipole is at 90° to E (θ₀ = 90°, cos θ₀ = 0).
  6. 6★
    So, U(θ) = −pE cos θ = −p·E.

★ key step

Dipole energy at key angles

Angle θU = −pE cos θEquilibrium
0° (p along E)−pE, the lowestStable
90°0Not in equilibrium (torque is pE)
180° (p against E)+pE, the highestUnstable

Worked example: energy of two charges

Problem

Charges of +2 μC and −3 μC are 30 cm apart in air. (a) Find the potential energy of the pair. (b) How much work is needed to separate them completely?

Working
  1. (a) U = kq₁q₂/r = 9 × 10⁹ × (2 × 10⁻⁶)(−3 × 10⁻⁶) ÷ 0.30.
  2. U = 9 × 10⁹ × (−6 × 10⁻¹²) ÷ 0.30 = −0.054 ÷ 0.30 = −0.18 J.
  3. (b) At infinite separation U = 0. Work needed = 0 − (−0.18 J) = +0.18 J.
Answer

(a) −0.18 J; (b) 0.18 J

Worked example: turning a dipole

Problem

A dipole of moment 2 × 10⁻⁸ C m lies along a uniform field of 5 × 10⁴ N C⁻¹. Find the work needed to turn it (a) through 90° and (b) through 180°.

Working
  1. pE = 2 × 10⁻⁸ × 5 × 10⁴ = 1 × 10⁻³ J.
  2. (a) W = pE(cos 0° − cos 90°) = 1 × 10⁻³ × (1 − 0) = 1 × 10⁻³ J.
  3. (b) W = pE(cos 0° − cos 180°) = 1 × 10⁻³ × (1 + 1) = 2 × 10⁻³ J.
Answer

(a) 1 × 10⁻³ J; (b) 2 × 10⁻³ J

In real life

The energy in the food you eat and in the petrol of a scooter is really electrostatic potential energy, stored in how the charges in molecules are arranged. Digestion or burning moves these charges to a lower-energy arrangement and releases the difference.

Exam angle

3 marks: “Derive an expression for the potential energy of an electric dipole in a uniform electric field. Find the work done in turning it from the stable to the unstable position.” W = ∫ pE sin θ dθ = pE(cos θ₀ − cos θ₁); with U(90°) = 0, U = −pE cos θ. From 0° to 180°: W = 2pE.

2 marks: “Three charges of +1 μC each sit at the corners of an equilateral triangle of side 10 cm. Find the potential energy of the system.” Three equal pairs: U = 3kq²/a = 3 × 9 × 10⁹ × (10⁻⁶)² ÷ 0.10 = 3 × 0.09 = 0.27 J.

1 marks: “In which orientation is the potential energy of a dipole in a uniform field the least?” When p is along E (θ = 0°): U = −pE.

Remember it

Count pairs, not charges: each pair once. Dipole energy is −pE cos θ: lowest when it lines up with the field.