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Unit VII · Atoms and molecules
6 min readConcept sheetPart I (1 mark), Part II (2 marks: define with an example) and Part III (4 marks: compare all three)

Isotopes, isobars and isotones

Isotopes share the same atomic number, isobars share the same mass number, and isotones share the same number of neutrons.

NeutronsNumber of neutrons = A − Z (mass number minus atomic number)
IsotopesSame Z, different A: H-1, H-2, H-3
IsobarsSame A, different Z: Ar-40, K-40, Ca-40
IsotonesSame neutrons: C-13 and N-14 (7 each)

Compare the three

TermWhat is the sameWhat is differentExamples
IsotopesAtomic number Z (number of protons); same elementMass number A (number of neutrons)H-1, H-2, H-3 (protium, deuterium, tritium; Z = 1); Cl-35 and Cl-37 (Z = 17)
IsobarsMass number AAtomic number Z; they are different elementsAr-40 (Z = 18), K-40 (Z = 19), Ca-40 (Z = 20)
IsotonesNumber of neutrons (A − Z)Both Z and AC-13 (6 p, 7 n) and N-14 (7 p, 7 n); Na-23 (11 p, 12 n) and Mg-24 (12 p, 12 n)

How to sort any pair of atoms

  1. 1
    Compare the atomic numbers (Z). If Z is the same, the atoms are isotopes.
  2. 2
    If Z differs, compare the mass numbers (A). If A is the same, they are isobars.
  3. 3
    If both differ, find neutrons = A − Z for each. If the neutrons are equal, they are isotones.

Worked example: K-39 and Ca-40

Problem

Potassium-39 has Z = 19. Calcium-40 has Z = 20. Find their neutrons and name the pair.

Working
  1. Formula: neutrons = A − Z
  2. K-39: 39 − 19 = 20 neutrons
  3. Ca-40: 40 − 20 = 20 neutrons
  4. Z differs (19 and 20) and A differs (39 and 40), but the neutrons are equal.
Answer

K-39 and Ca-40 are isotones, with 20 neutrons each.

Properties and uses

  • Isotopes have the same chemical properties (same number of electrons) but slightly different physical properties such as mass and density.
  • Isobars and isotones are different elements, so their chemical properties differ.
  • Uses of isotopes: cobalt-60 treats cancer, iodine-131 treats thyroid disease, carbon-14 dates old objects, uranium-235 is a nuclear fuel.
In real life

Hospitals use iodine-131 to test and treat thyroid problems and cobalt-60 to treat cancer. Heavy water, made with deuterium (H-2), is used in the reactors of the Madras Atomic Power Station at Kalpakkam near Chennai.

Exam angle

1 marks: “C-13 and N-14 both have 7 neutrons. Atoms like these are called ______.” Isotones.

2 marks: “Define isobars with an example.” Atoms of different elements with the same mass number but different atomic numbers, e.g. Ar-40 (Z = 18) and Ca-40 (Z = 20).

4 marks: “Distinguish between isotopes, isobars and isotones with one example each.” A three-row table: what is the same, what differs and one example each. Add neutrons = A − Z and one line on properties.

Remember it

isotoPes: same Protons. isobArs: same A (mass number). isotoNes: same Neutrons.