Why atoms combine: noble gases and the octet rule
Noble gases have 8 electrons in their outer shell (helium has 2), so they hardly react. Other atoms combine to reach this stable octet.
Outer shells of the noble gases
| Noble gas | Symbol | Atomic number | Configuration | Outer electrons |
|---|---|---|---|---|
| Helium | He | 2 | 2 | 2 |
| Neon | Ne | 10 | 2, 8 | 8 |
| Argon | Ar | 18 | 2, 8, 8 | 8 |
| Krypton | Kr | 36 | 2, 8, 18, 8 | 8 |
| Xenon | Xe | 54 | 2, 8, 18, 18, 8 | 8 |
| Radon | Rn | 86 | 2, 8, 18, 32, 18, 8 | 8 |
Why noble gases do not react
Noble gases do not usually form compounds. Early chemists called them inert gases, which means unreactive. Their outer shell is full: 8 electrons, or 2 for helium. A full outer shell is very stable, which means it does not easily change. Note: radon's symbol is Rn. Your NIOS lesson's table prints Ra, which is the symbol of radium.
The octet rule
Atoms such as hydrogen, sodium and chlorine do not have a full outer shell, so they react. They lose, gain or share electrons until each has 8 electrons in its outer shell, like the nearest noble gas. Hydrogen needs only 2, like helium. This is the octet rule (octet means a group of eight). It is the basic cause of chemical bonding.
Two ways to complete the octet
- Transfer of electrons from a metal to a non-metal gives an ionic bond. Example: sodium chloride.
- Sharing of electrons between two non-metal atoms gives a covalent bond. Example: hydrogen, H₂.
- Either way, the bonded atoms have less energy than the separate atoms. Lower energy means more stable.
- Metal atoms usually have 1, 2 or 3 outer electrons, so they lose them. Non-metal atoms usually have 4 to 7, so they gain or share electrons.
Stable or reactive? Read the outer shell
| Element (atomic number) | Configuration | Outer electrons | What it does |
|---|---|---|---|
| Neon (10) | 2, 8 | 8 | Stable: does not react |
| Argon (18) | 2, 8, 8 | 8 | Stable: does not react |
| Sodium (11) | 2, 8, 1 | 1 | Reacts: loses 1 electron |
| Magnesium (12) | 2, 8, 2 | 2 | Reacts: loses 2 electrons |
| Oxygen (8) | 2, 6 | 6 | Reacts: gains or shares 2 electrons |
| Chlorine (17) | 2, 8, 7 | 7 | Reacts: gains or shares 1 electron |
Neon in shop signs glows when electricity passes, but it never burns or reacts inside the tube. Argon fills ordinary filament bulbs because it does not react with the hot filament.
1 marks: “State the octet rule.” Atoms combine by losing, gaining or sharing electrons so that each has 8 electrons in its outermost shell, like a noble gas (2 for hydrogen).
2 marks: “Why do noble gases hardly form compounds? Name the noble gas that is stable with only 2 outer electrons.” Their outermost shell is already full (8 electrons, or 2 in helium). This arrangement is very stable, so they do not need to lose, gain or share electrons. Helium has 2.
2 marks: “Element X has atomic number 18 and element Y has atomic number 19. Which one reacts easily, and why?” X is 2, 8, 8: a full octet, so it is stable (argon). Y is 2, 8, 8, 1: it has one outer electron to lose, so Y (potassium) reacts easily.
Eight is great: atoms lose, gain or share electrons to reach the noble gas eight. Hydrogen is happy with two.